(2010). Chemistry of Phosphorus Ylides, Part 30. Reaction of Camphorquinone Derivatives with Active Phosphacumulenes and Stabilized Phosphonium Ylides. test, 53(2), 315-327. doi: 10.21608/ejchem.2010.1223
. "Chemistry of Phosphorus Ylides, Part 30. Reaction of Camphorquinone Derivatives with Active Phosphacumulenes and Stabilized Phosphonium Ylides". test, 53, 2, 2010, 315-327. doi: 10.21608/ejchem.2010.1223
(2010). 'Chemistry of Phosphorus Ylides, Part 30. Reaction of Camphorquinone Derivatives with Active Phosphacumulenes and Stabilized Phosphonium Ylides', test, 53(2), pp. 315-327. doi: 10.21608/ejchem.2010.1223
Chemistry of Phosphorus Ylides, Part 30. Reaction of Camphorquinone Derivatives with Active Phosphacumulenes and Stabilized Phosphonium Ylides. test, 2010; 53(2): 315-327. doi: 10.21608/ejchem.2010.1223

Chemistry of Phosphorus Ylides, Part 30. Reaction of Camphorquinone Derivatives with Active Phosphacumulenes and Stabilized Phosphonium Ylides

Egyptian Journal of Chemistry
Article 9, Volume 53, Issue 2, April 2010, Pages 315-327    PDF (453.38 K)
DOI: 10.21608/ejchem.2010.1223
Abstract
THE REACTION of the bifunctional camphorquinone(1) , its monophenylhydrazone (13) and monooxime (16) with the active phosphacumulenes (2) was performed. Phosphanylidene- cyclobutylidenes (5), azitidine bicyclo heptanones (14) and phosphanylidenes (17) were obtained, respectively. On the other hand, the stabilized phosphonium ylides (6) react with the above mentioned substrates (1, 13, and 16) to give the corresponding oxaphosphetane (8), phosphanylidene (10) oxatricycloundecadiene (12), azaphosphetidines (15) and the azatricyclo- undecadienone (19).
Keywords
Camphorquinone derivatives; phosphonium ylides; Phosphanylidene cyclobutylidenes; Oxaphosphetane and Azatricycloundecadienone
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