(2011). 1.4-Arylation of β-(4-acetylaminobenzoyl)acrylic Acid with Activated Aromatic Hydrocarbons under Friedel-Crafts Conditions and Some Studies with the Products. test, 54(1), 69-79. doi: 10.21608/ejchem.2011.1380
. "1.4-Arylation of β-(4-acetylaminobenzoyl)acrylic Acid with Activated Aromatic Hydrocarbons under Friedel-Crafts Conditions and Some Studies with the Products". test, 54, 1, 2011, 69-79. doi: 10.21608/ejchem.2011.1380
(2011). '1.4-Arylation of β-(4-acetylaminobenzoyl)acrylic Acid with Activated Aromatic Hydrocarbons under Friedel-Crafts Conditions and Some Studies with the Products', test, 54(1), pp. 69-79. doi: 10.21608/ejchem.2011.1380
1.4-Arylation of β-(4-acetylaminobenzoyl)acrylic Acid with Activated Aromatic Hydrocarbons under Friedel-Crafts Conditions and Some Studies with the Products. test, 2011; 54(1): 69-79. doi: 10.21608/ejchem.2011.1380

1.4-Arylation of β-(4-acetylaminobenzoyl)acrylic Acid with Activated Aromatic Hydrocarbons under Friedel-Crafts Conditions and Some Studies with the Products

Egyptian Journal of Chemistry
Article 5, Volume 54, Issue 1, February 2012, Pages 69-79    PDF (465.46 K)
DOI: 10.21608/ejchem.2011.1380
Abstract
THE BEHAVIUOR of 3-(4-acetylaminobenzoyl) prop-2-enoic acid 1 with m-xylene and\or p-xylene under Friedel-Craft,s reaction conditions yielded 2- ( 2,4-Dimethyl and/or 2,5-dimethyl ) phenyl-3-(4-acetylaminobenzoyl)propanoic acids (2a,b) and thia-Micheal of acid 1 afforded 2- phenyl sulfanyl-3-(4-acetylamino benzoyl propanoic acid (3). Interaction of acids 2,3 with N2H4 , AC2O, NH2OH.HCl and PhNHNH2, yielded pyridazinone 4 , Furanone 5 1, 2oxazine 6 and 2-phenyl pyridazinone derivatives, respectively. Treatment of pyridazinone 4 with different interesting alkyl halides afforded the pyridazine derivatives 8 .
Keywords
3-Aroyl prop-2-enoic acid. Pyridazinone. Furanone; oxazinone and Alkyl pyridazine
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