Osasona, I., Onyemari, J., Johnson, J., Siyanbola, T. (2022). Phosphoric Acid and Cashew Bark Extract Activated Carbons derived from Coconut (Cocos nucifera) Shells for Cr (VI) Adsorption. test, 65(6), 803-815. doi: 10.21608/ejchem.2021.47465.2980
Ilesanmi Osasona; Joshua Onyemari; Jonathan Abidemi Johnson; Tolutope Oluwasegun Siyanbola. "Phosphoric Acid and Cashew Bark Extract Activated Carbons derived from Coconut (Cocos nucifera) Shells for Cr (VI) Adsorption". test, 65, 6, 2022, 803-815. doi: 10.21608/ejchem.2021.47465.2980
Osasona, I., Onyemari, J., Johnson, J., Siyanbola, T. (2022). 'Phosphoric Acid and Cashew Bark Extract Activated Carbons derived from Coconut (Cocos nucifera) Shells for Cr (VI) Adsorption', test, 65(6), pp. 803-815. doi: 10.21608/ejchem.2021.47465.2980
Osasona, I., Onyemari, J., Johnson, J., Siyanbola, T. Phosphoric Acid and Cashew Bark Extract Activated Carbons derived from Coconut (Cocos nucifera) Shells for Cr (VI) Adsorption. test, 2022; 65(6): 803-815. doi: 10.21608/ejchem.2021.47465.2980

Phosphoric Acid and Cashew Bark Extract Activated Carbons derived from Coconut (Cocos nucifera) Shells for Cr (VI) Adsorption

Egyptian Journal of Chemistry
Article 68, Volume 65, Issue 6, June 2022, Pages 803-815    PDF (1.15 M)
Document Type: Original Article
DOI: 10.21608/ejchem.2021.47465.2980
Authors
Ilesanmi Osasona* 1; Joshua Onyemari1; Jonathan Abidemi Johnson1; Tolutope Oluwasegun Siyanbola2
1Department of Chemical Sciences, College of Sciences, Afe Babalola University, Ado - Ekiti, Nigeria
2Department of Chemistry, Covenant University, P.M.B. 1023, Ota, Nigeria
Abstract
THIS study was conducted to activate and characterize carbons prepared from coconut shells for subsequent adsorption of Cr (VI) from synthetic wastewater. The adsorption process was carried out through batch studies. The results showed that the process was pH, contact time and temperature dependent. The optimum pH for Cr (VI) adsorption was 2 for both cashew bark extract activated (CNAC1) and H3PO4 activated (CNAC2) carbons. Characterization of the activated carbons using Fourier Transform-Infrared Spectroscopy (FTIR) revealed that OH and C=O were some of the prominent functional groups involved in the adsorption of Cr (VI). The EDX analysis results confirmed the adsorption of Cr (VI) on the surfaces of the activated carbons (ACs). Furthermore, SEM characterization showed that the free ACs were coarser and more porous than their Cr (VI loaded counter-parts while elemental composition of the activated carbons showed that the samples were carbonaceous. The adsorption process was feasible and followed pseudo-first-order kinetic model. Generally, the efficiency of CNAC2 was higher than that of CNAC1. However, cashew bark extract could be used as an activating agent for the preparation of activated carbon from coconut shells for Cr (VI) adsorption because it is cheaper and eco-friendlier than H3PO4.
Keywords
Cashew bark extract; Activated carbon; Coconut Shells; Chemical Activation; Cr (VI)
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