Husna, A., Febrianti, F., Syah, H., Pangaribuan, R., Surbakti, T., Sihombing, J., Pulungan, A. (2022). Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel. test, 65(11), 61-67. doi: 10.21608/ejchem.2022.96526.4517
Adistya Fadhilah Husna; Fitria Febrianti; Habibie Helminan Syah; Rabiatul Adawiyah Pangaribuan; Tia Aulia Surbakti; Junifa Layla Sihombing; Ahmad Nasir Pulungan. "Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel". test, 65, 11, 2022, 61-67. doi: 10.21608/ejchem.2022.96526.4517
Husna, A., Febrianti, F., Syah, H., Pangaribuan, R., Surbakti, T., Sihombing, J., Pulungan, A. (2022). 'Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel', test, 65(11), pp. 61-67. doi: 10.21608/ejchem.2022.96526.4517
Husna, A., Febrianti, F., Syah, H., Pangaribuan, R., Surbakti, T., Sihombing, J., Pulungan, A. Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel. test, 2022; 65(11): 61-67. doi: 10.21608/ejchem.2022.96526.4517

Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel

Egyptian Journal of Chemistry
Article 8, Volume 65, Issue 11, November 2022, Pages 61-67    PDF (699.75 K)
Document Type: Original Article
DOI: 10.21608/ejchem.2022.96526.4517
Authors
Adistya Fadhilah Husna1; Fitria Febrianti1; Habibie Helminan Syah1; Rabiatul Adawiyah Pangaribuan1; Tia Aulia Surbakti1; Junifa Layla Sihombing2; Ahmad Nasir Pulungan* 1
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia
2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl.Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia
Abstract
Oil palm midrib are very abundant waste, especially in the North Sumatra. Lignocellulose contained in oil palm midrib can be used as a source of alternative energy raw materials. The purpose of this research is to produce bio-oil that can reduce the use of fossil fuels. Natural zeolite (ZAS) as a catalyst was activated by mineral acid and calcination with nitrogen gas. Impregnation of Ni and Fe into ZAS followed by calcination and oxidation process to obtained Ni-Fe/ZAS catalyst. The conversion of oil palm midrib powder into cellulose was carried out by delignification process with NaOH and bleaching. Then, the conversion of bio-oil is carried out by pyrolysis using the HDO process. Based on the results of the catalyst characterization and activity test showed that the Ni-Fe/ZAS catalyst had good characteristics and activity. Bio-oil from fiber is dominated by lignin derivatives, meanwhile cellulose bio-oil is dominated by furan derivatives. Hydrodeoxygenation using a Ni-Fe/ZAS catalyst on fiber produced slightly different compounds from bio-oil in HDO without a catalyst, especially in the reduction percentage of phenol area from 52.91% to 39.58%. Meanwhile, in HDO bio-oil from cellulose, there was an increase in the percent area of ​​phenol from 27.45% to 35.59%.
Keywords
Oil palm midrib; natural zeolite; catalyst; bio-oil; pyrolysis; hydrogenation
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