Synthesis and study conductmetrically parameters of trans hydroxyl-4-proline with vandyl complex and its biological activity | ||
| Egyptian Journal of Chemistry | ||
| Volume 65, Issue 132, December 2022, Pages 263-271 PDF (1.14 M) | ||
| Document Type: Review Articles | ||
| DOI: 10.21608/ejchem.2022.120565.5409 | ||
| Author | ||
| Radwa Tarek Rashad* | ||
| Physical chemistry, Misr Higher Institute for Engineering and Technology, mansoura | ||
| Abstract | ||
| This study aims to investigate thermodynamic parameters for nano VO (II) sulfate alone and with amino acid (H2Prol) to form complexes in the solutions, and metal complexe have been characterized on the basis of elemential analysis, electronic spectra, IR spectra and various physico chemical study. The measurements of vandyl sulphate conductance have happened in binary mixed solvent with ethanol in different mass fraction 0.0, 0.2 and 0.4 (W/W) (EtOH-H2O) at four different temperatures from 298.15 to 313.15K (with a step of 5 K). The experimental data obtained by using the Fuoss-Shedlovsky extrapolation technique. All thermodynamic parameters for association were calculated, also we studied the effect of hydrogen bond formation in solution. Furthermore, biological activity measurements are executed, which benefits in determining the factors impacting the thermodynamic parameters | ||
| Keywords | ||
| Limiting molar conductance; Ion-pair association Constants; Binary Mixed solvents; Walden product; Association constant | ||
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