Synthesis and characterization of New binuclear complexes of Fe(II), Co(II), Zn (II), and Cd(II) with Schiff base ligands derived from Isatins and amines, spectroscopic study and evaluation of their biological activity | ||
| Egyptian Journal of Chemistry | ||
| Volume 66, Issue 2, February 2023, Pages 411-424 PDF (1.55 M) | ||
| Document Type: Original Article | ||
| DOI: 10.21608/ejchem.2022.134668.5926 | ||
| Authors | ||
| Ahlaam Albayati* ; Salah Sheet; Ahmed Haydari | ||
| General Directorate of Education in Nineveh , Iraq | ||
| Abstract | ||
| The research includes the preparation of eight new binuclear complexes of Schiff base ligands prepared from azatine derivatives ethylenediamine-bis(aza) and 1,3-propanediamine-bis(aza) and 1,3-propandiamine-bis(aza). And also the aliphatic like (Propandiamine) with the metals iron (II), cobalt (II), zinc (II) and cadmium (II). The complexes were also measured by spectroscopic methods UV-Vis, electronic spectra, infrared, as well as by XRD. The results showed the formation of iron complexes with a square pyramid shape, while cobalt complexes with an octahedral shape. The biological activity of complexes with fungi was estimated. Their effect was clearly visible. | ||
| Keywords | ||
| binuclear; Azatine; ethylenediamine-bis-Azatine; 1; 3-propane-diamine-bis-(Isa) | ||
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