Physical properties and optical basicity of transition metal-doped borate glasses | ||
| Bulletin of Faculty of Science, Zagazig University | ||
| Article 11, Volume 2022, Issue 2, July 2022, Pages 121-128 PDF (1.08 M) | ||
| Document Type: Original Article | ||
| DOI: 10.21608/bfszu.2022.136030.1131 | ||
| Authors | ||
| Hamsa Mohamed AboBakr* 1; Abd Elrahman Eldaly2; Mohamed Abdo1; Mohamed saad3 | ||
| 1physics department, faculty of science, Zagazig university | ||
| 2Physics department, faculty of science, Zagazig University, | ||
| 3basic sciences department, faculty of engineering,Sinai university | ||
| Abstract | ||
| Abstract [ To study various properties of cobalt cations on glasses, a new borate 62B2O3-(20-x)ZnO-18Na2O-x CoO glass system, with x = 1.5,1,0.5 and 0 mol.% was prepared by using the melt quenching technique. Traditional methods and usual formulas were used to calculate the molar volume (Vm) and measurement of density (ρ).Optical bascity (Λth) was determined using the formula suggested by Duff and Ingram. The dependence of density (⍴), molar volume (Vm), ion concentration (N), polaron radius (rp), field strength (F), inter atomic distance (ri) ,optical bascity(Λth), electronic polarizability (α0−2) and electronegativity (Χav) on Co2+cations content were analyzed. The trend of density, field strength, ion concentration, electronegativity with composition shows an increasing behavior with CoO content, while molar volume, inter atomic distance, polaron radius, optical basicity and electronic polarizability exhibit a decrement behavior . so that these obtained results nominate these cobalt-borate glasses for promising applications such as optical devices. ] | ||
| Keywords | ||
| Borate glasses; Transition metals; Physical properties; Optical basicity | ||
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