Synthesis and Characterization of Some Novel Selenoazo Derivatives | ||
| Sohag Journal of Sciences | ||
| Volume 8, Issue 3, September 2023, Pages 347-351 PDF (345.11 K) | ||
| Document Type: Regular Articles | ||
| DOI: 10.21608/sjsci.2023.212498.1082 | ||
| Authors | ||
| Amer A Amer* ; Sham M. M. El-Saghier; Bahgat R. M. Hussein | ||
| Department of Chemistry, Faculty of Science, Sohag University, Sohag 82524, Egypt | ||
| Abstract | ||
| A novel series of Se-heterocyclic compounds, which containing azo-dye and organoselenium moieties, have been synthesized by the reaction of 4,6-diamino-2-(methylselanyl)pyridine-3-carbonitrile (1) with aromatic diazonium chloride salts. Furthermore, oxobutanamide 3 was obtained via N-acetylation of methylselanyl pyridine 1 by ethyl acetoacetate. Product 3 was used as a starting material to synthesize aryl hydrazones 4a and 4b. However, an unprecedented series of thiapyridine derivatives 7a and 7b was produced through a one-pot multicomponent reaction of methylselanyl pyridine 1 with chloroacetyl chloride and thiophenol derivatives. | ||
| Keywords | ||
| pyridine; azo dye; methylselanyl; oxobutanamide; Arylhydrazones; thiapyridine; multi-component | ||
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