(2023). Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.. test, 61(3), 38-44. doi: 10.21608/mjcc.2023.411553
. "Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.". test, 61, 3, 2023, 38-44. doi: 10.21608/mjcc.2023.411553
(2023). 'Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.', test, 61(3), pp. 38-44. doi: 10.21608/mjcc.2023.411553
Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.. test, 2023; 61(3): 38-44. doi: 10.21608/mjcc.2023.411553

Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.

Mansoura Journal of Chemistry
Volume 61, Issue 3, May 2023, Pages 38-44    PDF (1.26 M)
Document Type: Original Article
DOI: 10.21608/mjcc.2023.411553
Abstract
In this work, new Cd2+, and Hg2+ complexes of 4-pyridyl thiosemicarbazon Schiff base derived from beta-hydroxy carbonyl has been synthesized and isolated. The structure of the new complexes was proposed by numerous techniques such as elemental (CHN) analyses, FT-IR. TG and DTG thermal decomposition for Cd2+ complex was carried out. Thermodynamic and kinetic parameters were calculated via Coats-Redfern and Horowitz-Metzger equations. And finally, the modeling using DFT calculations was fully studied.
Keywords
4-pyridyl thiosemicarbazon; DFT; beta-hydroxy carbonyl
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