Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)

doi:10.21608/mjcc.2021.412837

	Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)
Mansoura Journal of Chemistry
Volume 54, Issue 4, December 2021, Pages 6-11 PDF (1.17 M)
DOI: 10.21608/mjcc.2021.412837
Abstract
The electrochemical behavior of cadmium ions on glassy carbon electrodes in two-step processes involves reduction at -0.95V and oxidation at -0.6 VVs. Ag/AgCl electrodes has been reported. The cyclic voltammetry data for cadmium ions using potassium chloride as supporting electrolyte in 50 % Demso-H2O (V/V) shows enhanced currents in the absence and presence of ligand N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide(H₂BTHB). Different cyclic voltammetry solvation data were obtained for cadmium ions in the absence and presence of (H₂BTHB).The obtained cyclic voltammetry and thermodynamic data prove the complexation reaction between the cadmium ions and the used ligand.
Keywords
Cyclic voltammetry; Redox reaction; Electron rate constant; Thermodynamic; kinetic parameters

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