Supramolecular design and biological activity of coordination polymer based on dimethyltin (IV) and N-donor ligand | ||
| Delta Journal of Science | ||
| Article 3, Volume 39, Issue 1, June 2018, Pages 18-22 PDF (1.53 M) | ||
| Document Type: Research and Reference | ||
| DOI: 10.21608/djs.2018.138902 | ||
| Authors | ||
| Safaa Eldin H. Etaiw; Dina M. Abd El-Aziz; Elham A. Ali | ||
| Chemistry Department, Faculty of Science, Tanta University, Tanta 31527, Egypt. | ||
| Abstract | ||
| The supramolecular polymer of the type [Me2SnCl2L], 1, L = 2,2'-bipyridine (2,2'-bpy), has been synthesized by the reaction of dimethyltin (IV) dichloride and 5-nitroisophthallic acid in the presence of sodium ethoxide and 2,2'-bpy. The compound was structurally characterized by elemental analysis, FT-IR spectra and X-ray single crystal. The x-ray data exhibited 1:1 stoichiometry for the dimethyltin dichloride: 2,2'-bpy ligands. The structure of 1 extends along the a-axis in a parallel way forming 1D-chains via H-bonds while they further propagate creating 2D- network via extensive H-bonds. The biological activity against some fungi and bacterial microorganisms has been also studied. | ||
| Keywords | ||
| Organotin; 2; 2'-bipyridine; X-ray structure; Biological Activities | ||
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