Fauziah, S., Gafur, A., Soekamto, N., Taba, P., Sapar, A. (2021). Synthesis and Characterization of Molecularly Imprinted Polymers of Di-(2-Ethylhexyl) Phthalate Using The Precipitation Polymerization Method. test, 64(5), 2385-2392. doi: 10.21608/ejchem.2021.44820.2912
St Fauziah; Andi Magattang Gafur; Nunuk Soekamto; Paulina Taba; Ajuk Sapar. "Synthesis and Characterization of Molecularly Imprinted Polymers of Di-(2-Ethylhexyl) Phthalate Using The Precipitation Polymerization Method". test, 64, 5, 2021, 2385-2392. doi: 10.21608/ejchem.2021.44820.2912
Fauziah, S., Gafur, A., Soekamto, N., Taba, P., Sapar, A. (2021). 'Synthesis and Characterization of Molecularly Imprinted Polymers of Di-(2-Ethylhexyl) Phthalate Using The Precipitation Polymerization Method', test, 64(5), pp. 2385-2392. doi: 10.21608/ejchem.2021.44820.2912
Fauziah, S., Gafur, A., Soekamto, N., Taba, P., Sapar, A. Synthesis and Characterization of Molecularly Imprinted Polymers of Di-(2-Ethylhexyl) Phthalate Using The Precipitation Polymerization Method. test, 2021; 64(5): 2385-2392. doi: 10.21608/ejchem.2021.44820.2912

Synthesis and Characterization of Molecularly Imprinted Polymers of Di-(2-Ethylhexyl) Phthalate Using The Precipitation Polymerization Method

Egyptian Journal of Chemistry
Article 15, Volume 64, Issue 5, May 2021, Pages 2385-2392    PDF (700.29 K)
Document Type: Review Articles
DOI: 10.21608/ejchem.2021.44820.2912
Authors
St Fauziah* 1; Andi Magattang Gafur2; Nunuk Soekamto2; Paulina Taba2; Ajuk Sapar3
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Indonesia
2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University
3Department of Chemistry, Faculty of Mathematics and Natural Sciences, Tanjungpura University
Abstract
Molecularly Imprinted Polymers (MIP) is a synthetic functional material that can recognize target molecules selectively. This study aims to synthesize and characterize MIP and its performance by precipitation polymerization method using methacrylic acid (MAA), ethylene glycol dimethacrylate (EGDMA), and di-(2-Ethylhexyl) phthalate (DEHP). Characterization of MIP was conducted by FTIR, SEM-EDS, SAA, and UV-Vis spectrophotometer. The effect of concentration and time on MIP adsorption ability against DEHP was also determined. SEM shows that MIP_DEHP_MAA-co-EGDMA surface morphology is arranged from more uniform, less tight, and more fine granules than NIP_MAA-co-EGDMA. FTIR characterization of MIP and NIP (Non-Imprinted Polymers) shows absorption bands of functional groups were –OH, C-H, C=O, and –C=C. SAA characterization shows MIP surface area is 137.660 m2/g, total pore volume 0.1555 cc/g, and an average pore radius 22.59 Å that indicates as mesopore material. MIP_DEHP_MAA-co-EGDMA (AE) adsorbed DEHP better than NIP_MAA-co-EGDMA. The difference value of the adsorbed DEHP (qe) was 0.212 mg/g
Keywords
Synthesis; diethylhexyl phthalate; molecular imprinting polymer; precipitation
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