(2020). Synthesis and characterization of new binuclear metal complexes from 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide. test, 48(2), 31-36. doi: 10.21608/mjcc.2020.412876
. "Synthesis and characterization of new binuclear metal complexes from 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide". test, 48, 2, 2020, 31-36. doi: 10.21608/mjcc.2020.412876
(2020). 'Synthesis and characterization of new binuclear metal complexes from 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide', test, 48(2), pp. 31-36. doi: 10.21608/mjcc.2020.412876
Synthesis and characterization of new binuclear metal complexes from 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide. test, 2020; 48(2): 31-36. doi: 10.21608/mjcc.2020.412876

Synthesis and characterization of new binuclear metal complexes from 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide

Mansoura Journal of Chemistry
Volume 48, Issue 2, May 2020, Pages 31-36    PDF (874.48 K)
Document Type: Original Article
DOI: 10.21608/mjcc.2020.412876
Abstract
The bimetallic complexes of 2,2'-malonylbis(N-phenylhydrazine-1-carbothioamide) have been prepared and characterized via different spectral tools. The ligand can exist in keto-thioketo form and chelated to the metal ion in binegative tetradentate and neutral tetradentate manners as indicated by the infrared spectra. The electronic spectra and magnetic moment measurements showed that the Cu(II) complex has a square planar geometry while the Co(II) and Ni(II) have octahedral structure. The ESR spectrum of the Cu(II) complex confirmed the square planar configuration. Thermal gravimetric analysis (TGA) for the isolated complexes was performed to explain its thermal stability
Keywords
Malonohydrazide; Phenyl isothiocyanate; Metal complexes; ESR spectra; TGA
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